中国首例铁氧化物-铜-金-铀-稀土型矿床的厘定及其成矿演化   总被引：21，自引：0，他引：21  

李泽琴  胡瑞忠  王奖臻  刘家军  李朝阳  刘玉平  叶霖 《矿物岩石地球化学通报》2002,21(4):258-260

通过对拉拉矿床物共生组合、矿物生成顺序、矿石特征的研究，发现其矿石物以磁铁矿为主，铁和铜的硫化物次之，并含有大量稀土矿物和自然金。拉拉矿床至少经历了两期成矿作用：早期为区域变质成矿作用，晚期为热液成矿作用。早期形成Fe-REE-P矿化，晚期为Cu-Mo-Au-Co-(U)矿化。根据这些特征，首次指出该矿床属于铁氧化物-铜-金-铀-稀土型矿床，而不是以往所称的块状硫化物型铜矿。  相似文献   

Hydrothermal Redistribution of Rare—Earth Elements in Pingxiang Dacite,Guangxi     

顾尚义  万国江  毛健全  张启厚 《中国地球化学学报》2002,21(2):170-174

Distribution of the rare-earth elements (REE) in dacite has been studied so as to get a better understanding of the migration behavior of REE during alteration. Both unaltered and altered samples were collected in an unpolluted area of Guangxi Zhuang Autonomous Region, southwest China. The REE concentrations were analyzed by ICP-MS. It is concluded that the REE were enriched during dacite alteration in varying degrees. The chondrite-normalized REE patterns of altered samples approximately maintain the characteristics of unaltered samples. However, if we normalize the REE concentrations of altered samples with unaltered dacite, fractionation of REE will appear. The LREE are more enriched than HREE in all altered samples with the LREE possibly precipitated as carbonate minerals. Both positive and negative Eu anomalies exist. Enrichment, immobility and depletion are noticed for the element Lu. Heavy mineral alteration, difference in stability constant between carbonate LREE and HREE complexes, downward migration of weathering fluid and microenvironment change may be responsible for the fractionation of REE in the altered dacite.  相似文献   

GEOCHEMICAL EFFECTS OF MAJOR ELEMENTS DURING FLUID-ROCKS INTERACTION IN MARINWOBO FAULT IN THE SOUTH MARGIN AREAS OF ALTAI MOUNTAINS     

ZHAO Zhi-zhong ZENG Qiao-song BI Hua 《大地构造与成矿学(英文版)》2002,(2):68-75

There are four types of metamorphic rocks in the Marinwobo fault, i. e, cataclasite, mylonite,mictosite and migmatitic granite, and the formation of these rocks is due to the progressive metamorphism of the pyroclastics. The fluids play a very important role in the metamorphic process of these rocks in the Marinwobo fault, the most important feature is that the fluids not only result in the migration of the major elements of the deformation rocks, but also result in the volume loss of the deformation rocks in the deformation process. Thus the migration laws of the major elements in different stages of the progressive metamorphic process are discussed according to mass balance equations. Finally, the quantitative analysis of the mass loss and volume loss of the different rocks the in Marinwobo fault is discussed in this paper.  相似文献   

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析     

薛克勤  赵月凤  董清雷 《华北地质》2002,(Z1)

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。  相似文献   

吉林省大横路铜、钴矿床地质特征及控矿因素     

郭文秀  刘建民 《华北地质》2002,(Z1)

大横路地区出露地层主要为元古界老岭群大栗子组和珍珠门组的低绿片岩相 -高绿片岩相到低角闪岩相的变质岩系 ,北部有少量英云闪长岩 -奥长花岗岩和表壳岩残块。侵入岩主要以燕山期基性 -中基性为主。铜钴矿床产于含碳绢云千枚岩中 ,矿体长 36 0～ 140 0m ,宽 95～ 80 0m ,厚 3～ 10 8.7m ,呈层状、似层状、分枝状 ,矿石以浸染状为主 ,次为脉状、网脉状。矿床属多期多成因类型 ,主要受大栗子组地层、北东向断裂构造和变质作用控制 ,并有岩浆热液的叠加。  相似文献   

Gold Mineralization and Occurrence of Sinter in the Hoshino Area, Fukuoka Prefecture, Japan     

Ahmed Belhadi    Tetsuya Nakanishi  Koichiro Watanabe  Eiji Izawa 《Resource Geology》2002,52(4):371-380

Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al₂O₃, K₂O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested.  相似文献   

Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga     

Yasuhiro KATO  Takashi KANO  Keitaro KUNUGIZA 《Resource Geology》2002,52(2):101-110

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.  相似文献   

Aeromagnetic signatures over western Marie Byrd Land provide insight into magmatic arc basement, mafic magmatism and structure of the Eastern Ross Sea Rift flank   总被引：1，自引：0，他引：1  

F. Ferraccioli  E. Bozzo  D. Damaske 《Tectonophysics》2002,347(1-3)

Aeromagnetic signatures over the Edward VII Peninsula (E7) provide new insight into the largely ice-covered and unexplored eastern flank of the Ross Sea Rift (RSR). Positive anomalies, 10–40 km in wavelength and with amplitudes ranging from 50 to 500 nT could reveal buried Late Devonian(?)–Early Carboniferous Ford Granodiorite plutons. This is suggested by similar magnetic signature over exposed, coeval Admiralty Intrusives of the Transantarctic Mountains (TAM). Geochemical data from mid-Cretaceous Byrd Coast Granite, contact metamorphic effects on Swanson Formation and hornblende-bearing granitoid dredge samples strengthen this magnetic interpretation, making alternative explanations less probable. These magnetic anomalies over formerly adjacent TAM and western Marie Byrd Land (wMBL) terranes resemble signatures typically observed over magnetite-rich magmatic arc plutons. Shorter wavelength (5 km) 150 nT anomalies could speculatively mark mid-Cretaceous mafic dikes of the E7, similar to those exposed over the adjacent Ford Ranges. Anomalies with amplitudes of 100–360 nT over the Sulzberger Bay and at the margin of the Sulzberger Ice Shelf likely reveal mafic Late Cenozoic(?) volcanic rocks emplaced along linear rift fabric trends. Buried volcanic rock at the margin of the interpreted half-graben-like “Sulzberger Ice Shelf Block” is modelled in the Kizer Island area. The volcanic rock is marked by a coincident positive Bouguer gravity anomaly. Late Cenozoic volcanic rocks over the TAM, in the RSR, and beneath the West Antarctic Ice Sheet exhibit comparable magnetic anomaly signature reflecting regional West Antarctic Rift fabric. Interpreted mafic magmatism of the E7 is likely related to mid-Cretaceous and Late Cenozoic regional crustal extension and possible mantle plume activity over wMBL. Magnetic lineaments of the E7 are enhanced in maximum horizontal gradient of pseudo-gravity, vertical derivative and 3D Euler Deconvolution maps. Apparent vertical offsets in magnetic basement at the location of the lineaments and spatially associated mafic dikes and volcanic rocks result from 2.5D magnetic modelling. A rift-related fault origin for the magnetic lineaments, segmenting the E7 region into horst and graben blocks, is proposed by comparison with offshore seismic reflection, marine gravity, on-land gravity, radio-echo sounding, apatite fission track data and structural geology. The NNW magnetic lineament, which we interpret to mark the eastern RSR shoulder, forms the western margin of the “Alexandra Mountains horst”. This fundamental aeromagnetic feature lies on strike with the Colbeck Trough, a prominent NNW half-graben linked to Late Cretaceous(?) and Cenozoic(?) faulting in the eastern RSR. East–west and north–north–east to NE magnetic trends are also imaged. Magnetic trends, if interpreted as reflecting the signature of rift-related normal faults, would imply N–S to NE crustal extension followed by later northwest–southeast directed extension. NW–SE extension would be compatible with Cenozoic(?) oblique RSR rifting. Previous structural data from the Ford Ranges have, however, been interpreted to indicate that both Cretaceous and Cenozoic extensions were N–S to NE–SW directed.  相似文献   

Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

从流体包裹体研究探讨金属矿床成矿条件   总被引：29，自引：4，他引：29  

芮宗瑶  李荫清  王龙生  王义天 《矿床地质》2003,22(1):13-23

根据作者多年来对流体包裹体的研究成果，参考了国内外的研究结论，提出了一个新的成矿流体分类方案，并评述了我国若干典型金属矿床的研究状况，由此探讨了金属矿床的形成机制。  相似文献